Once you’ve taken the time to understand Art. 90 and read (a few times) the definitions in Art. 100, you have an overview of what the NEC is about, and you can “speak the language.”
A bit more preparation work will prove valuable. Turn to Informative Annex H. This is also referred to as Art. 80, but it is not part of the requirements of the NEC. Still, it will help you understand and correctly apply those requirements. You can think of it as illuminating some legal aspects of electrical work.
Annex H provides definitions of three key roles: authority having jurisdiction, chief electrical inspector, and electrical inspector. It tells you how the NEC applies to new or existing buildings, and it covers permits. It also tells you how to appeal a decision to the Electrical Board. You may need to take this avenue if you and the electrical inspector (and chief electrical inspector) cannot agree. You’ll learn about how the Board is structured and what some of its rules are, too. Annex H also covers other useful topics.