Q. Can Table 310.15(B)(6) be used to size service conductors for a duplex?
A. Maybe. Table 310.15(B)(6) is only suitable to size 3-wire, single-phase, 120/240V service or feeder conductors (including neutral conductors) that serve as the main power feeder for an individual dwelling unit. So you can size the individual service conductors to each unit using this table, but not the service conductors for both units.
About the Author

Mike Holt
Mike Holt is the owner of Mike Holt Enterprises (www.MikeHolt.com), one of the largest electrical publishers in the United States. He earned a master's degree in the Business Administration Program (MBA) from the University of Miami. He earned his reputation as a National Electrical Code (NEC) expert by working his way up through the electrical trade. Formally a construction editor for two different trade publications, Mike started his career as an apprentice electrician and eventually became a master electrician, an electrical inspector, a contractor, and an educator. Mike has taught more than 1,000 classes on 30 different electrical-related subjects — ranging from alarm installations to exam preparation and voltage drop calculations. He continues to produce seminars, videos, books, and online training for the trade as well as contribute monthly Code content to EC&M magazine.